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ASTM A182 F53 Super Duplex Steel Flanges

UNS S32750  |  2507 Super Duplex  |  DIN 1.4410  |  PREN ≥40  |  YS 550 MPa  |  Seawater Qualified


ASTM A182 F53 super duplex 2507 flange manufacturer India
UNS S32750 2507 super duplex steel flanges supplier

What Is ASTM A182 F53 (UNS S32750 / 2507 Super Duplex)?


ASTM A182 Grade F53 is a super duplex stainless steel standardised under UNS S32750 and DIN 1.4410 (X2CrNiMoN25-7-4), widely known by its commercial designation 2507 super duplex. The "25-07" designation refers to its nominal 25% chromium and 7% nickel content — significantly higher than standard duplex 2205 (22% Cr, 5% Ni). Combined with 4% molybdenum and 0.28% nitrogen, F53 achieves a PREN of approximately 40–48, placing it firmly in the seawater-qualified corrosion resistance category.

F53 offers three simultaneous performance advantages that make it the preferred choice for the most demanding environments:

  • Extreme pitting resistance (PREN ≥40) — qualifies for seawater immersion, FGD, and high-chloride chemical service where standard duplex 2205 is borderline or insufficient
  • High strength (YS ≥550 MPa) — approximately 3.2× that of Grade 316L (YS 170 MPa) and 22% stronger than standard 2205 (YS 450 MPa), enabling weight and wall-thickness savings in pressure-retaining components
  • NACE / sour-service compliance — ISO 15156-3 permits F53 in H₂S-bearing offshore environments at hardness up to 36 HRC, making it one of the few materials combining high strength, seawater corrosion resistance, and sour-service acceptance

Tesco Steel & Engineering manufactures A182 F53 flanges in all standard types (weld neck, slip-on, blind, socket weld, threaded, lap joint) in sizes ½″–56″ NB to ASME B16.5 and B16.47, and supplies globally to 96 countries across 6 continents.

ASTM A182 F53 Chemical Composition (UNS S32750 / 2507)


ElementMin (%)Max (%)Role & Significance
Chromium (Cr)24.026.0Primary corrosion barrier; 25% Cr is the hallmark of super duplex grades
Nickel (Ni)6.08.0Austenite stabiliser; 7% Ni maintains phase balance at high Cr/Mo
Molybdenum (Mo)3.05.0Enhances pitting resistance 3.3× per unit; 4% Mo is key to PREN ≥40
Nitrogen (N)0.240.32Strongest austenite stabiliser; contributes 16× to PREN; improves strength
Carbon (C)0.030Extra-low C prevents sensitisation during welding
Silicon (Si)0.80Deoxidiser; controlled to avoid sigma phase promotion
Manganese (Mn)1.20Austenite stabiliser; controlled to maintain PREN
Copper (Cu)0.50Minor corrosion benefit in reducing acids
Phosphorus (P)0.035Controlled for toughness
Sulfur (S)0.020Controlled for corrosion resistance and hot workability
Super Duplex vs Standard Duplex Composition:

F53 (2507): 25Cr + 7Ni + 4Mo + 0.28N → PREN ~43
F51 (2205): 22Cr + 5Ni + 3Mo + 0.14N → PREN ~35
The step up from F51 to F53 adds ~1.5 PREN per percentage point of additional Mo and Cr, crossing the critical PREN ≥40 seawater threshold.

Mechanical Properties — ASTM A182 F53 (2507 Super Duplex)


PropertyRequirementImperial
Tensile Strength (UTS)≥795 MPa≥115 ksi
Yield Strength (0.2% offset)≥550 MPa≥80 ksi
Elongation in 2 in (50 mm)≥15%≥15%
Hardness (max)310 HBW32 HRC
NACE/ISO 15156-3 hardness limit350 HBW36 HRC
Heat Treatment ConditionSolution annealed 1060–1100°C + water quench
Ferrite content (target)40–60% ferrite (duplex balance)
Impact (Charpy V-notch)27 J min at −50°C (transverse)
Strength Perspective:
  • Grade 316L: YS ≈170 MPa — F53 is 3.2× stronger
  • F51 / 2205 (standard duplex): YS 450 MPa — F53 is 22% stronger
  • F52 / 3RE60 (lean duplex): YS 415 MPa — F53 is 32% stronger
  • F55 / Zeron 100: YS 550 MPa — comparable strength, different alloy system (W-alloyed)

PREN Calculation & Seawater Corrosion Qualification


PREN Formula for F53 / UNS S32750

PREN = %Cr + 3.3 × %Mo + 16 × %N

At nominal composition (25% Cr, 4% Mo, 0.28% N):
PREN = 25 + (3.3 × 4) + (16 × 0.28) = 25 + 13.2 + 4.48 = 42.7

At maximum composition (26% Cr, 5% Mo, 0.32% N):
PREN = 26 + 16.5 + 5.12 = 47.6

At minimum composition (24% Cr, 3% Mo, 0.24% N):
PREN = 24 + 9.9 + 3.84 = 37.7 (minimum bound)

Industry thresholds: PREN ≥23 mild  |  PREN ≥29 moderate Cl⁻ process  |  PREN ≥35 offshore splash zone  |  PREN ≥40 full seawater immersion ← F53 meets this

Critical Pitting Temperature (CPT) Comparison — ASTM G48 Method E

GradePRENCPT (°C, FeCl₃)Seawater Suitability
316L / F316L~23<0°CNot suitable (pits in ambient seawater)
F52 / 3RE60~29~15–25°CBrackish water / non-immersion only
F51 / 2205~35~25–35°CSplash zone; marginal for immersion
F53 / 2507 ★~43>50°CFull seawater immersion — qualified
F55 / Zeron 100~42>50°CFull seawater immersion — qualified

Super Duplex Grade Selection

F51 / 2205

UNS S31803 — Standard Duplex

PREN ~35

YS: 450 MPa

Offshore splash zone, moderate Cl⁻; not suitable for seawater immersion

F53 / 2507 ★

UNS S32750 — Super Duplex

PREN ~43

YS: 550 MPa

Full seawater immersion — offshore, FGD, desalination

F55 / Zeron 100

UNS S32760 — Super Duplex

PREN ~42

YS: 550 MPa

Alternative super duplex; W-alloyed for additional pitting resistance

Operating Temperature Limits & Phase Stability


Temperature RegimeRangeNotes
Minimum service temperature−50°C (−58°F)Impact-tested; good Charpy V-notch toughness ≥27 J at −50°C
Recommended continuous maximum280°C (536°F)Conservative limit; sigma-phase kinetics faster in 2507 than 2205
ASME B16.5 Group 2.3 design limit315°C (600°F)Allowable stress decreasing above 280°C
475°C embrittlement zone300–500°CFaster in super duplex due to higher Cr+Mo ferrite; AVOID
Sigma phase zone600–1000°CMore rapid in 2507 than 2205; forms within minutes at 850°C — strict weld heat input control required
Solution anneal (only permissible HT)1060–1100°C + WQHigher anneal temperature than standard duplex (1020°C) due to higher alloy content
⚠ Faster Sigma Phase Kinetics in Super Duplex:

In 2507 super duplex, sigma phase can form in as little as 1–2 minutes at 850°C during welding — significantly faster than in 2205 (~5–10 minutes). This is why the maximum interpass temperature for F53 welding is 100°C (compared to 150°C for F51) and why heat input per pass must be carefully controlled. Each weld pass must be allowed to cool before the next pass is deposited.

Welding ASTM A182 F53 Super Duplex Flanges


⛔ Critical Welding Rules for Super Duplex — Read First

  • Do NOT use ER2209 filler — ER2209 is for standard duplex (2205) only. Using it on 2507 will give insufficient pitting resistance and incorrect ferrite balance in the weld metal.
  • Max interpass 100°C — stricter than standard duplex (150°C) due to faster sigma-phase kinetics in super duplex alloys.
  • PWHT in 300–1050°C is prohibited — causes 475°C embrittlement or sigma-phase precipitation. Solution anneal (1060–1100°C + WQ) is the only permissible thermal treatment.
  • Measure ferrite after welding — FN below 30 risks SCC; FN above 65 risks toughness loss and sigma-phase susceptibility.
Welding ParameterRequirement for F53 / UNS S32750
PreheatNot required. Surfaces must be dry and free of moisture, oil, and chloride contamination.
Maximum interpass temperature100°C (100°C for super duplex — stricter than 150°C for standard duplex F51)
Filler metal (GTAW/GMAW)AWS ER2594 (25Cr-9.5Ni-3.5Mo-0.25N) — over-alloyed vs base metal to compensate for N loss
Filler metal (SMAW)AWS E2594-XX (matching ER2594 composition for stick welding)
Shielding gas (GTAW)Ar + 2–3% N₂; nitrogen addition essential to maintain austenite balance in super duplex welds
Post-weld heat treatmentPROHIBITED in 300–1050°C range. Full solution anneal (1060–1100°C + WQ) only if required for rework.
Ferrite Number target (weld metal)FN 30–65 per WRC-1992 diagram
Heat input control0.5–1.5 kJ/mm recommended; avoid excessive heat input that promotes sigma phase
Post-weld corrosion testASTM G48 Method A or E on weld coupons recommended for critical seawater service
Procedure qualificationASME Section IX or EN ISO 15614-1; include hardness survey and ferrite measurement

Phase Stability & Embrittlement in F53 Super Duplex


PhenomenonTemperature RangeRate vs 2205EffectRecovery
475°C Embrittlement 300–500°C Faster in 2507 (higher Cr ferrite) Spinodal decomposition α→α' + α; catastrophic toughness loss; increased hardness Solution anneal 1060–1100°C + WQ
Sigma (σ) Phase 600–1000°C Much faster in 2507; forms in 1–2 min at 850°C Fe-Cr-Mo intermetallic at boundaries; embrittlement and severe pitting corrosion Solution anneal 1080–1100°C + WQ
Chi (χ) Phase 700–900°C More prevalent in high-Mo grades Mo-rich intermetallic; similar to sigma phase effects; reduces PREN locally Solution anneal + WQ
Cr₂N Precipitation 700–950°C Accelerated by high N content of 2507 Chromium nitride at boundaries; sensitisation; reduces corrosion resistance in HAZ Rapid cooling; solution anneal if needed

The higher alloy content of F53 (more Cr, Mo, and N than F51) increases the thermodynamic driving force for all these transformations. This is why F53 welding demands tighter thermal discipline than standard duplex — but also why, in the correctly annealed condition, its corrosion resistance exceeds all other common duplex grades.

Available F53 Super Duplex Flange Types & Specifications


F53 2507 super duplex weld neck flange manufacturer

Weld Neck (WNRF)

Long-radius tapered hub — preferred for high-pressure offshore and subsea service. Excellent fatigue performance. Available in RTJ facing for subsea flange connections.

F53 2507 super duplex slip-on flange

Slip-On (SORF)

Economical for above-waterline process piping where full fatigue resistance is not required. Fillet-welded inside and outside.

F53 2507 super duplex blind flange

Blind Flanges (BLF)

Heavy-wall blinds for high-pressure seawater and chemical isolation. Rated in all pressure classes. Often supplied in RTJ for offshore tie-in points.

ASTM A182 F53 Flange Specifications
Flange StandardASTM A182 Grade F53 / ASME SA182 Grade F53
Size Range½″ NB to 56″ NB (DN 15 to DN 1400)
Pressure Classes (B16.5)Class 150, 300, 600, 900, 1500, 2500
Pressure Classes (B16.47)Class 150, 300, 400, 600, 900 — Series A (MSS SP-44) & Series B (API 605)
P-T GroupASME B16.5 Group 2.3
Schedules / Wall thicknessSCH 10S, 40S, 80S, XS, XXS, STD, Sch 20, 40, 80, 160
Facing TypesRaised Face (RF), Flat Face (FF), Ring Type Joint (RTJ) — RTJ preferred for offshore
DIN/EN Equivalent1.4410 (X2CrNiMoN25-7-4) — EN 10028-7, EN 10088-3
Offshore standardNORSOK M-630, MDS D58 (2507 flange material data sheet)
Heat TreatmentSolution annealed 1060–1100°C + water quench (mandatory)
Testing & InspectionPMI, chemical analysis, tensile, hardness, Charpy impact at −50°C, ferrite measurement, ASTM G48 corrosion test, dimensional, visual, hydrostatic (on request)

▶ View A182 F53 Flange Dimensions (ASME B16.5 / B16.47)

Corrosion Resistance of F53 / 2507 Super Duplex


Seawater & Chloride Pitting

PREN ~43 and CPT >50°C (ASTM G48 Method E) qualify F53 for full seawater immersion, SWRO high-pressure seawater, and chloride concentrations up to seawater levels. This is the primary reason for specifying 2507 over standard duplex in offshore and marine applications.

Chloride Stress Corrosion Cracking

The ferritic phase in F53 is inherently immune to chloride SCC — the mechanism responsible for austenitic stainless steel failures in hot chloride service. F53 provides safe operation in aggressive chloride environments up to approximately 150°C, well above the failure temperature of 316L.

FGD (Flue Gas Desulfurization) Service

F53 is one of the standard materials for FGD absorber tower internals and slurry piping, where chloride concentrations reach 30,000–80,000 mg/L and pH can drop to 3–4. Standard 2205 (F51) is borderline in high-Cl⁻ FGD service; 2507 (F53) provides the necessary resistance margin.

Sour Service (H₂S + Chloride)

ISO 15156-3 (NACE MR0175) permits F53 super duplex in H₂S-containing service up to 36 HRC hardness. Combined with PREN ≥40, this makes F53 unique among commercially available stainless alloys — simultaneously handling high-chloride corrosion AND sour-service requirements for offshore production systems.

Complete Piping System — UNS S32750 Companion Materials


ComponentSpecificationGrade
FlangesASTM A182 / ASME SA182Grade F53
Seamless & Welded PipeASTM A790 / ASME SA790Grade S32750
Buttweld FittingsASTM A815 / ASME SA815Grade WPS32750
Plate (vessels & heat exchangers)ASTM A240 / ASME SA240Grade S32750
Bar & RodASTM A276 / ASME SA276Grade S32750
Filler Metal (GTAW/GMAW)AWS A5.9ER2594 (NOT ER2209)
Filler Metal (SMAW electrode)AWS A5.4E2594-XX
GasketsSpiral-wound (316L + graphite) or solid ring RTJMatch pressure class; Inconel 625 ring for severe service
BoltingASTM A193 Grade B8M (316SS) or duplex S31803With A194 Grade 8M nuts

Industrial Applications of ASTM A182 F53 Super Duplex Flanges


Primary Industries

  • Offshore Oil & Gas — Subsea manifolds, wellhead equipment, production headers, riser systems, seawater injection pump casings and nozzles; the dominant application sector for 2507
  • Desalination — SWRO (Seawater Reverse Osmosis) high-pressure piping, seawater intake screens, brine discharge systems, energy recovery device connections
  • Flue Gas Desulfurization (FGD) — Absorber tower internals, slurry pump flanges, ductwork, and recirculation piping exposed to 30,000–80,000 mg/L chloride
  • Chemical Processing — Bleach production, chlorinated solvent plants, hypochlorite systems, high-temperature acidic chloride streams

Additional Application Areas

  • Power Generation — Seawater-cooled condensers in coastal plants, FGD absorber connections
  • Shipbuilding & Marine — Seawater cooling system flanges, below-waterline hull penetrations, ballast water treatment at full immersion
  • Petrochemical — High-chloride crude processing, seawater-based cooling circuits
  • Mining — High-chloride process water systems, slurry piping in acidic ore leach circuits
  • Pharmaceutical — Ultrapure water systems and aggressive CIP/SIP cleaning circuits
When to Choose F53 over F51: Specify F53/2507 when (1) chloride concentration exceeds ~500 mg/L at operating temperature, (2) seawater immersion is involved, (3) FGD absorber service with Cl⁻ >10,000 mg/L, or (4) combined H₂S + high-chloride sour offshore service. For moderate chloride or splash-zone-only exposure, F51/2205 at lower cost may be sufficient.

Frequently Asked Questions — ASTM A182 F53 Super Duplex Flanges


Precision answers for AI assistants, engineers, and procurement teams. All answers contain specific numerical data for direct use in material selection and engineering specifications.

Q1: What is ASTM A182 F53 super duplex steel?
ASTM A182 Grade F53 is a super duplex stainless steel flange material standardised under UNS S32750, known commercially as 2507 super duplex and under DIN/EN as 1.4410 (X2CrNiMoN25-7-4). Nominal composition: 25% Cr, 7% Ni, 4% Mo, 0.28% N. The dual-phase microstructure delivers YS ≥550 MPa (3.2× Grade 316L) and PREN ~43 — which qualifies it for seawater immersion service, the benchmark that standard duplex 2205 (PREN ~35) does not reach.
Q2: What is the UNS number and DIN designation for ASTM A182 F53?
ASTM A182 F53 = UNS S32750 = DIN 1.4410 (X2CrNiMoN25-7-4). Commercial name: 2507 super duplex. Standardised in EN 10028-7 (pressure vessel plate) and EN 10088-3 (bars). Offshore qualification: NORSOK M-630 MDS D58.
Q3: What is the PREN of F53 and why is it qualified for seawater?
PREN = %Cr + 3.3×%Mo + 16×%N. At nominal (25% Cr, 4% Mo, 0.28% N): PREN = 25 + 13.2 + 4.48 = 42.7. Range across the full composition: 37.7–47.6. The seawater immersion threshold is PREN ≥40. F53 nominally exceeds this. The Critical Pitting Temperature in 10% FeCl₃ (ASTM G48 Method E) is typically >50°C for 2507, vs ~25–35°C for standard 2205 (F51) and <0°C for 316L.
Q4: What is the difference between F53 (2507) and F51 (2205)?
Key differences: F53 PREN ~43 vs F51 ~35 (seawater-qualified vs splash-zone only); F53 YS 550 MPa vs F51 450 MPa (22% stronger); F53 Cr 25% vs F51 22%; F53 Mo 4% vs F51 3%; F53 N 0.28% vs F51 0.14%; F53 max interpass 100°C vs F51 150°C; F53 filler ER2594 vs F51 ER2209. F53 is specified for seawater immersion, FGD high-chloride, and combined sour/chloride offshore service. F51 is sufficient for moderate chloride and splash-zone marine service at lower cost.
Q5: What is the maximum service temperature for F53 super duplex flanges?
Continuous service: −50°C to 280°C. ASME B16.5 Group 2.3 design limit: 315°C (with reduced allowable stress). The practical upper limit is 280°C due to the faster sigma-phase kinetics of 2507 vs standard duplex — meaning sigma can form rapidly above 280°C even in relatively short exposure times. Exposure in the 300–1050°C range is strictly prohibited.
Q6: What filler metal is used for welding F53 (2507) super duplex flanges?
AWS ER2594 (25% Cr, 9.5% Ni, 3.5% Mo, 0.25% N) for GTAW/GMAW; E2594-XX for SMAW. ER2209 must NOT be used — it is under-alloyed for 2507 and will produce a weld metal with insufficient pitting resistance. Shielding gas: Ar + 2–3% N₂. Max interpass: 100°C. Target FN: 30–65. No preheat required.
Q7: Is PWHT required for F53 super duplex flanges?
No — and conventional PWHT is prohibited. Any exposure to 300°C–1050°C causes 475°C embrittlement (300–500°C) or sigma-phase precipitation (600–1000°C). Due to the high alloy content of 2507, sigma forms faster than in 2205 — even brief accidental heating above 300°C is problematic. The only permissible thermal treatment is full solution anneal at 1060–1100°C + water quench, applied only for heavily reworked sections, not routine welds.
Q8: What are the NACE MR0175 / ISO 15156-3 limits for F53 super duplex?
Per ISO 15156-3 Table A.3 for UNS S32750 in H₂S-containing environments: maximum hardness 36 HRC (350 HBW) for base metal, HAZ, and weld metal. ASTM A182 F53 product hardness limit is 310 HBW (32 HRC), which is within the NACE limit. This high hardness tolerance (vs 22 HRC for carbon steel) reflects the duplex microstructure's inherent sulfide stress cracking resistance. F53 is therefore suitable for sour offshore applications combining H₂S and high chloride — a combination that eliminates most competing materials.
Q9: Which standards cover A182 F53 and its companion materials?
Flanges: ASTM A182 / ASME SA182 Grade F53  |  Pipe: ASTM A790 Grade S32750  |  Fittings: ASTM A815 Grade WPS32750  |  Plate: ASTM A240 Grade S32750  |  Bar: ASTM A276 Grade S32750  |  Dimensions: ASME B16.5 (NPS ½–24) / ASME B16.47 (NPS 26–60)  |  P-T Group: ASME B16.5 Group 2.3  |  EN: 1.4410, EN 10028-7 / EN 10088-3  |  Offshore: NORSOK M-630 MDS D58.
Q10: Which industries use ASTM A182 F53 super duplex steel flanges?
Primary: Offshore oil & gas (subsea manifolds, wellhead, seawater injection — dominant application); Desalination (SWRO high-pressure seawater systems); FGD (absorber towers and slurry piping at 30,000–80,000 mg/L Cl⁻); Chemical processing (bleach, hypochlorite, high-Cl⁻ streams); Marine below-waterline (full seawater immersion). F53 is specified when the application requires PREN ≥40 (seawater), YS ≥550 MPa (structural efficiency), and NACE sour-service compliance simultaneously.

ASTM A182 F53 Super Duplex Flange Price & Availability


Tesco Steel & Engineering maintains stock of ASTM A182 F53 (UNS S32750 / 2507) flanges in common sizes and pressure classes. Custom dimensions, special facings (RTJ, FF), NACE-certified, and third-party-inspected material (Bureau Veritas, Lloyd's, DNV, SGS) are available. All material is supplied with full EN 10204 3.1 or 3.2 mill test reports.

Submit your enquiry with size, pressure class, schedule, facing, quantity, and special testing requirements (NACE, NORSOK, impact test, G48 corrosion test) for the fastest response.

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A182 F53 Quick Specs

GradeA182 F53
UNSS32750
Commercial Name2507 Super Duplex
DIN / EN1.4410
TypeSuper Duplex SS
Cr content24–26%
Ni content6–8%
Mo content3–5%
N content0.24–0.32%
PREN≥40 (nom. ~43)
UTS (min)795 MPa
YS (min)550 MPa
Elongation≥15%
Hardness (max)310 HBW / 32 HRC
B16.5 Group2.3
Service Temp−50°C to 280°C
NACE hardness≤36 HRC

PREN Grade Ladder

316L / F316LPREN ~23
F52 / 3RE60PREN ~29
F51 / 2205PREN ~35
F53 / 2507 ★PREN ~43
F55 / Zeron 100PREN ~42

PREN ≥40 = seawater immersion qualified
F53 exceeds this threshold

Welding Quick-Ref

PreheatNot required
Max interpass100°C ⚠
Filler (GTAW)ER2594
Filler (SMAW)E2594-XX
NOT to useER2209 ✗
PWHTPROHIBITED
FN target30–65
Shielding gasAr + 2–3% N₂

⚠ Avoid These Temperatures

475°C embrittlement300–500°C
Sigma phase (fast!)600–1000°C
Solution anneal only1060–1100°C + WQ

Note: Sigma forms in 1–2 min at 850°C in 2507 — faster than in 2205.

Related Duplex Grades

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